The role of attractive interactions in self-diffusion

Recently, an alternative approach to self-diffusion in atomic liquids was p roposed by one of us [Vergeles, hi., Szamel, G. Chem. Phys. 1999, 110, 3009 ]. This approach is applicable where the concept of binary collisions break s down and the self-diffusion coefficient is small. Predictions from this m ethod are in quantitative agreement with molecular dynamics (MD) simulation s, over a broad range of densities and temperatures, for an atomic liquid i nteracting with a repulsive r(-12) potential. Here we extend this approach to include attractive interactions; we study a liquid interacting with the Lennard-Jones (LJ) potential. Theoretical predictions are compared to MD si mulations results. To clarify the role of attractive interactions, we compa re LJ results with those obtained with the repulsive part of the LJ potenti al. Conclusions about the role of the attractive forces in self-diffusion a re discussed.