Lineshapes in magnetic resonance spectra

Citation
R. Berger et al., Lineshapes in magnetic resonance spectra, J PHYS-COND, 12(44), 2000, pp. 9347-9360
Citations number
26
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
12
Issue
44
Year of publication
2000
Pages
9347 - 9360
Database
ISI
SICI code
0953-8984(20001106)12:44<9347:LIMRS>2.0.ZU;2-B
Abstract
In magnetic resonance, and in particular, in superparamagnetic resonance st udies at variable temperatures, a correlation between the apparent resonanc e magnetic field and the apparent linewidth is often observed. In order to account for this correlation, we consider the resonance Lineshapes resultin g from different phenomenological equations of damped motion of the magneti c moments in the cases of a linear paramagnet and of a perfect soft ferroma gnet. The Bloch-Bloembergen, modified Bloch, Gilbert, Landau-Lifshitz and C allen equations are analysed. In most cases we obtain analytical expression s for the apparent resonance-field shift. Finally we report an experimental variable-temperature study of the superparamagnetic resonance of ultrafine Fb(2)O(3) particles in sol-gel glass. Computer simulations using the Landa u-Lifshitz lineshape provide good fits of the resonance spectra at differen t temperatures for the same magnetic and morphological parameters of the pa rticles.