Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand

Authors
Giesbrecht, GR Gebauer, A Shafir, A Arnold, J
Citation
Gr. Giesbrecht et al., Alkali-metal complexes of a triazacyclononane-functionalized tetramethylcyclopentadienyl ligand, J CHEM S DA, (22), 2000, pp. 4018-4020
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
1470479X → ACNP
Issue
22
Year of publication
2000
Pages
4018 - 4020
Database
ISI
SICI code
1470-479X(2000):22<4018:ACOATT>2.0.ZU;2-B
Abstract
Reaction of (1,4-diisopropyl-1,4,7-triazacyclononane)Li with C5Me4HSiMe2Cl yields the new donor-functionalized ligand, [C5Me4SiMe2(tacn)]H; the alkali -metal salts [C5Me4SiMe2(tacn)]M (M=Li, Na, K) are obtained upon reaction w ith BuLi, NaN(SiMe3)(2) or KN(SiMe3)(2).