Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

Authors
Destarac, M Charmot, D Franck, X Zard, SZ
Citation
M. Destarac et al., Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents, MACRO RAPID, 21(15), 2000, pp. 1035-1039
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
10221336 → ACNP
Volume
21
Issue
15
Year of publication
2000
Pages
1035 - 1039
Database
ISI
SICI code
1022-1336(20001023)21:15<1035:DAURAC>2.0.ZU;2-1
Abstract
Control of the radical polymerization acrylates, styrene and vinyl acetate has been achieved using novel dithiocarbamates as reversible addition-fragm entation chain transfer agents. The key parameter for the control with N,N- disubstituted (A) or cyclic (B) dithiocarbamates was round to be the conjug ation of the lone of pair of electrons of the nitrogen atom with carbonyl o r aromatic groups.