We have studied a method of pretilting liquid crystal on the surface of a s
ubstrate by photoaligning the polyimide substrate containing azo type chrom
ophores. The liquid crystal molecules were pretilted by inducing anisotropy
in the cell substrate with anisotropic photopumping of the chromophores. U
sing the crystal rotation method, we have investigated the orientational or
dering of 5CB liquid crystal on a photoaligned azo-polyimide substrate.