Yk. Han et al., Synthesis of new poly(silicate esters) with disperse red 1 and their application as optical data storage materials, MOLEC CRYST, 349, 2000, pp. 75-78
New silicate ester monomer was synthesized by the reaction of 3-methacrylox
ypropylmethyldichlorosilane with disperse red I in methylene chloride. The
monomer was polymerized with a radical initiator to produce the correspondi
ng homopolymer and copolymers. These polymers were found to be excellent as
reversible optical information recording media for data storage and retrie
val through a trans-cia isomerization of the azobenzene groups by Ar Laser
irradiation.