Polyarylates (PARs) with high glass transition temperature (Tg) are used fo
r photonic device applications. Optical properties are investigated, and it
indicates that the PARs show high thermal stability as well as high optica
l transparency. Electron-beam lithography can be performed using the PAR th
in films, and high resolution surface relief gratings are fabricated by dir
ect electron-beam writing technique together with thermal development.