Synthesis and luminescent properties of hyperbranched poly(P-phenylene)s by molecular architecture engineering

Authors
Shin, SH Oh, DJ Kim, HK
Citation
Sh. Shin et al., Synthesis and luminescent properties of hyperbranched poly(P-phenylene)s by molecular architecture engineering, MOLEC CRYST, 349, 2000, pp. 423-426
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS → ACNP
Volume
349
Year of publication
2000
Pages
423 - 426
Database
ISI
SICI code
Abstract
synthesized by both Suzuki reaction and a nickel-catalyzed Grignard couplin g reaction. P(4)8 and P(4)10 showed the UV absorption band at the longer wa velength than P(3)8 and P(3)10, even though they have the same number of co nsecutive phenyl groups. Photoluminescent (PL) spectra of P(4)8 and P(4)10 showed a blue emission at 490-496 nm, while P(3)8 and P(3)10 thin films sho wed a maximum PL peak around 420-440 nm in the deep blue region.