Cross-conjugated chromophores: Synthesis of iso-polydiacetylenes with donor/acceptor substitution

Citation
Sc. Ciulei et Rr. Tykwinski, Cross-conjugated chromophores: Synthesis of iso-polydiacetylenes with donor/acceptor substitution, ORG LETT, 2(23), 2000, pp. 3607-3610
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
3607 - 3610
Database
ISI
SICI code
1523-7060(20001116)2:23<3607:CCSOIW>2.0.ZU;2-F
Abstract
[GRAPHICS] The iterative construction of cross-conjugated donor (D), acceptor (A), and donor-acceptor (D-A) substituted iso-polydiacetylene (iso PDA) oligomers h as been achieved utilizing palladium catalyzed cross-coupling techniques. S tructure-property relationships for these compounds have been analyzed for cross conjugated pi -electronic communication as a result of contributions from donor, acceptor, or donor-acceptor functionalization.