Electron-energy-loss spectroscopy characterization of the sp(2) bonding fraction within carbon thin films

When using electron-energy-loss spectroscopy (EELS) to quantify the sp(2)/s p(3) bonding fraction in thin film carbon, the spectrum taken from the film must be compared to that of a suitable known standard. In contrast to the work of Berger [S. D. Berger and D. R. McKenzie, Philos. Mag. Lett. 57, 285 (1988)], C-60 fullerite is used in this work as the standard since highly oriented pyrolytic graphite (HOPG) is highly anisotropic, and can therefore lead to preferential orientation effects in EELS. It was found that C60 ha d a shoulder on the high-energy side of the 1s --> pi* peak, which was cent ered at 287 eV. In theory, many Gaussian peaks can be fitted to the near ed ge structure (NES) of the energy-loss spectrum. In practice, we show that o nly three, centered at energies of 285, 287, and 293 eV, are necessary for semiquantitative analysis. The 285 eV peak is indicative of the sp(2) bondi ng fraction; the second peak at 287 eV is attributed to molecular structure within the sample; the third at 293 eV is determined by sp(3) bonding cont ributions in the sample. We show that by fitting these three peaks to C-60 fullerite and evaporated amorphous carbon (a-C), that the a-C has a 0.99 sp (2) bonding fraction compared with the C-60 fullerite standard. The importa nce of considering the 287 eV peak in highly sp(2) bonded amorphous carbon is further illustrated by analysis of a-C:H:N thin films.