Electron paramagnetic resonance of Cu2+(d(9)) has been detected optically i
n the visible and near-infrared luminescence of wurtzite GaN. Its effective
S = 1/2 spin Hamiltonian parameters are g(\\) = +/-0.20(5), g(perpendicula
r to) = + 1.549(1), and \(63)A(\\)\ = 550(50) MHz, and \(63)A(perpendicular
to)\ = 570(5) MHz. A crystal field theory of the g values is presented, wh
ich identifies the ion as substitutional on the Ga sublattice. Possible mec
hanisms for its presence in the luminescence are discussed.