Coulomb explosion (CE) is identified as the mechanism of ion ejection under
low fluence ultrashort pulse laser ablation of crystalline Al2O3 The ion m
oments are equal during "gentle" ablation. This is explained by impulsive C
E from the surface region lasting similar to1 ps. The onset of "strong" abl
ation leads to a decrease in the measured ion velocitics. The kinetic energ
ies rather than the momenta of the ions become equal. This regime is associ
ated with strong plasma light emission and crater formation.