Gamma decays from excited states in the T-z= -1/2 nucleus Fe-51 have been o
bserved for the first time. The differences in excitation energies as compa
red with those of the mirror partner, Mn-51, have been interpreted in terms
of Coulomb effects and the resulting Coulomb energy differences (CED) can
be understood intuitively in terms of particle-alignment effects. A new CED
effect has been observed, in which different CED trends have been measured
for each signature of the rotational structures that characterize these mi
nd-f(7/2) shell nuclei. Large-scale fp-shell model calculations have been u
sed to compute the trends of the CED as a function of spin. The result of c
omparing these calculations with the data demonstrates an ability to reprod
uce the fine details of the Coulomb effects with a precision far greater th
an has been previously achieved.