The Sunyaev-Zel'dovich (SZ) effect associated with pressure fluctuations of
the large scale structure gas distribution will be probed with current and
upcoming wide-field small angular scale cosmic microwave background experi
ments. We study the generation of pressure fluctuations by baryons which ar
e present in virialized dark matter halos, with overdensities greater than
or similar to 200 and by baryons present in overdensities less than or simi
lar to 10. For collapsed halos, assuming the gas distribution is in hydrost
atic equilibrium with matter density distribution, we predict the pressure
power spectrum and bispectrum associated with the large scale structure gas
distribution by extending the dark matter halo approach which describes th
e density field in terms of correlations between and within halos. The proj
ected pressure power spectrum allows a determination of the resulting SZ po
wer spectrum due to virialized structures. The unshocked photoionized baryo
ns present in smaller overdensities trace the Jeans-scale smoothed dark mat
ter distribution. They provide a lower limit to the SZ effect due to large
scale structure in the absence of massive collapsed halos. We extend our ca
lculations to discuss higher order statistics, such as bispectrum and skewn
ess in SZ data. The SZ-weak lensing cross correlation is suggested as a pro
be of correlations between dark matter and baryon density fields, while the
probability distribution functions of peak statistics of SZ halos in wide
field CMB data can be used as a probe of cosmology and non-Gaussian evoluti
on of large scale pressure fluctuations.