We report the first observations of superlattices in thermal convection. Th
e superlattices are selected by a four-mode resonance mechanism that is qua
litatively different from the three-mode resonance responsible for complex-
ordered patterns observed previously in other nonequilibrium systems. Numer
ical simulations quantitatively describe both the pattern structure and the
stability boundaries of superlattices observed in laboratory experiments.
In the presence of the inversion symmetry, superlattices are found numerica
lly to bifurcate supercritically directly from conduction or from a striped
base state.