Orientation dependence of the mechanism of deformation, i.e., slip and twin
ning, was studied at 300 K on single crystals of Hadfield steel. It was sho
wn that mechanical twinning in [(1) over bar 11], [(1) over bar 44], and [0
11] crystals is developed upon tension from the very early deformation stag
es. The high values of Theta in [(1) over bar 11] crystals are related to t
he development of twinning on several twinning systems; in the [ (1) over b
ar 44] and [011] crystals, the early stages of deformation are connected wi
th twinning in a single system a/6[(2) over bar 11](111), and the passage t
o the operation of several twinning systems is accompanied by an increase i
n Theta. In [012], [(1) over bar 23], and [(1) over bar 13] orientations, t
he early stages of deformation are determined by slip; later, a change of t
he mechanism of deformation from slip to twinning occurs. For the first tim
e, we revealed mechanical twinning upon tension of [001] crystals and showe
d that there is an orientational dependence of resolved shear stresses rela
ted to the orientational dependence of the mechanisms of deformation by sli
p and twinning. Dislocation mechanisms of twin nucleation in Hadfield steel
are suggested.