Ss. Seomun et al., A new class of spatial light modulator using a crosslinkable azobenzene nematic liquid crystal, POLYM ADV T, 11(8-12), 2000, pp. 579-582
We studied how the orientation of photoreactive molecules is influenced by
the crosslinked polymer wall formed on the alignment surface in crosslinkab
le azobenzene nematic liquid crystal cells and developed a novel concept of
spatial light modulator. Just on the surface irradiated Ar ion laser, the
crosslinked polymer wall was spontaneously fabricated. The optical microsco
pe observation, when the intensity of observation light increases, liquid c
rystal molecules in the area with the crosslinked polymer wall can switch b
etween homogeneous and homeotropic state. The response time and the thresho
ld value are able to be regulated by the degree of crosslinking of azobenze
ne liquid crystal molecules. I has been concluded that the photoinduced swi
tching of this device is originated from the competition between the attenu
ated anchoring force tuned by the crosslinked polymer wall and the molecula
r reorientation via the tuans-cis-trans photoisomerization cycles of the az
obenzene moieties. Copyright (C) 2000 John Wiley & Sons, Ltd.