The microwave properties of single crystalline LaAlO3, LSAT ((LaAlO3)(
0.3)-(Sr2AlTaO6)(0.7)), rutile (TiO2), and polycrystalline Al2O3 were
investigated employing dielectric resonator techniques. LaAlO3 (epsilo
n(r) = 23.7) exhibits a frequency dependent maximum of tan delta at ab
out 70 K, which call be explained by defect dipole relaxation. This le
ads to a variation of tan delta at 9 GHz and 77 K from 5.10(-6) to 2.1
0(-5), the lowest values were achieved with Verneuil grown crystals. L
SAT (epsilon(r) = 22.8) exhibits an even more pronounced maximum with
absolute values in the 10(-4) range. For rutile (epsilon(r) = 108) we
measured a monotonous increase of tans with temperature, which can be
explained by intrinsic losses due to phonons. The loss tangent of Ti-d
oped polycrystalline, sintered Al2O3 was found to be only 4-10(-6) at
10 GHz and 77 K. Except LSAT the materials investigated so far provide
a large potential for applications as dielectric resonators shielded
by high temperature superconducting (HTS) films.