Isobaric vapour-liquid equilibrium of binary mixtures of some cyclic ethers with chlorocyclohexane at 40.0 and 101.3 kPa

Citation
S. Rodriguez et al., Isobaric vapour-liquid equilibrium of binary mixtures of some cyclic ethers with chlorocyclohexane at 40.0 and 101.3 kPa, THERMOC ACT, 362(1-2), 2000, pp. 153-160
Citations number
20
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
THERMOCHIMICA ACTA
ISSN journal
00406031 → ACNP
Volume
362
Issue
1-2
Year of publication
2000
Pages
153 - 160
Database
ISI
SICI code
0040-6031(20001113)362:1-2<153:IVEOBM>2.0.ZU;2-7
Abstract
Isobaric vapour-liquid equilibrium data for the binary systems formed by te trahydrofuran, tetrahydropyran, 2-methyl-tetrahydrofuran, and 2,5-dimethyl- tetrahydrofuran with chlorocyclohexane have been measured at 40.0 and 101.3 kPa using a dynamic recirculating still. All experimental data were checke d for thermodynamic consistency by means of the Van Ness method. The system s studied present slightly deviations from ideal behaviour. None of them sh ow azeotrope. The VLE data have been satisfactorily correlated with the equ ations of Wilson, NRTL and UNIQUAC. Predictions with the ASOG and UNIFAC gr oup contribution methods are included. (C) 2000 Elsevier Science B.V. All r ights reserved.