Bismuth(V) iron(III) tris(phosphate) oxide

Authors
Benabad, A Bakhous, K Cherkaoui, F Holt, EM
Citation
A. Benabad et al., Bismuth(V) iron(III) tris(phosphate) oxide, ACT CRYST C, 56, 2000, pp. 1292-1293
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
11
Pages
1292 - 1293
Database
ISI
SICI code
0108-2701(200011)56:<1292:BITO>2.0.ZU;2-H
Abstract
(Bi0.4Fe3O)-Fe-V-O-III(PO4)(3) crystallizes with two Fe atoms (one on an in version centre and one on a mirror plane) displaying octahedral geometry an d a third Fe atom (on a mirror plane) with trigonal bipyramidal coordinatio n. Fe atoms are seen in oxygen-bridged chains. Bi-V atoms are found in the interstitial sites between these chains. Bi shows sevenfold coordination, w ith Bi-O distances between 2.357 (7) and 2.529 (6) Angstrom.