Dichlorobis[2-(o-tolyliminiomethyl)-phenolato-O]zinc(II)

Authors
Ulku, D Arici, C Tahir, MN Atakol, O
Citation
D. Ulku et al., Dichlorobis[2-(o-tolyliminiomethyl)-phenolato-O]zinc(II), ACT CRYST C, 56, 2000, pp. 1298-1299
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
11
Pages
1298 - 1299
Database
ISI
SICI code
0108-2701(200011)56:<1298:D>2.0.ZU;2-R
Abstract
In the mononuclear title compound, [ZnCl2(C14H13NO)(2)], the Zn-II ion is l ocated on a twofold axis of the monoclinic space group so that the whole mo lecule has a twofold symmetry. The Zn-II ion has a tetrahedral coordination consisting of two chlorine ions and the O atoms of the ligands. The coordi nation angles around zinc have values between 102.89 (8) (O-Zn-O) and 115.8 3 (5)degrees (Cl-Zn-O). The Zn-O and Zn-Cl bond lengths are 1.977 (2) and 2 .2401 (7) Angstrom, respectively. There are intra- and intermolecular hydro gen bonds in the structure.