Intra- and intermolecular C-H center dot center dot center dot pi interactions in bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N-3,S]-nickel(II)

Authors
Raj, SSS Fun, HK Wu, J Tian, YP Xie, FX Shao, ZH Li, SL
Citation
Sss. Raj et al., Intra- and intermolecular C-H center dot center dot center dot pi interactions in bis[benzyl 3-(fluoren-9-ylidene)dithiocarbazato-N-3,S]-nickel(II), ACT CRYST C, 56, 2000, pp. 1321-1322
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
11
Pages
1321 - 1322
Database
ISI
SICI code
0108-2701(200011)56:<1321:IAICCD>2.0.ZU;2-E
Abstract
The title compound, [Ni(C21H15N2S2)(2)], has a novel cis configuration with two fluorene moieties on the same side. The Ni atom is in a square-planar configuration. The molecular packing is stabilized by intramolecular stacki ng between the fluorene moieties and extensive C-H . . . pi interactions.