We report detections of weak emission lines in the red spectral region of s
harp-lined chemically normal and peculiar (HgMn) late-B type stars from hig
h spectral resolution and high signal-to-noise data. Most emission lines or
iginate from high-excitation states of the ions Cr II and Mn II, with other
s likely to be attributed to Ti II and Fe II. The emission is observed to e
xtend over the entire line profile width for rotational velocities up to 18
km s(-1), implying that it originates within the same rotational framework
as the absorption line spectrum. Within the sample no obvious correlation
is noted for the presence of emission with regard to stellar effective temp
erature or luminosity. A dependence upon element abundance is evident from
the absence of Mn II emission for HgMn stars for which the manganese enhanc
ement is greater than 1.3 dex. This trend is mildly reinforced by the chrom
ium emission spectrum being most developed amongst stars richer in chromium
. We postulate that the Cr II and Mn LI emissions in the red spectral regio
n arise from a selective excitation process involving hydrogen Ly alpha pho
ton energies.