A multi-step process for the achievement of highly oriented, (100) tex
tured diamond films on silicon using flat flame deposition has been de
veloped. First, a bias-enhanced technique was used to achieve oriented
nuclei on a Si (100) substrate in a microwave plasma reactor. Substra
tes were then transferred to the combustion system and rapidly grown i
nto coalesced (100) films at a growth rate of 4-5 mu m/h. X-ray textur
e analysis was used to characterize the films. It showed a 12 degrees
misalignment of the crystallites with respect to the surface normal, w
hile the azimuthal misalignment was measured to be 20 degrees.