New luminescent and redox-active homometallic dinuclear iridium(III), ruthenium(II) and osmium(II) complexes prepared by metal-catalyzed coupling reactions
Pm. Griffiths et al., New luminescent and redox-active homometallic dinuclear iridium(III), ruthenium(II) and osmium(II) complexes prepared by metal-catalyzed coupling reactions, CHEM COMMUN, (23), 2000, pp. 2297-2298
Four new homometallic dinuclear Ir-III, Ru-II and Os-II complexes are prepa
red and their luminescence properties and redox behavior are reported; the
bis-phenathroline bridging ligand is found to isolate the two components of
each dinuclear system because of its unusual nonplanar structure.