The first unambiguous determination of a nitrosyl-to-nitrite conversion inan iron nitrosyl porphyrin

Authors
Cheng, L Powell, DR Khan, MA Richter-Addo, GB
Citation
L. Cheng et al., The first unambiguous determination of a nitrosyl-to-nitrite conversion inan iron nitrosyl porphyrin, CHEM COMMUN, (23), 2000, pp. 2301-2302
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
2000
Pages
2301 - 2302
Database
ISI
SICI code
1359-7345(2000):23<2301:TFUDOA>2.0.ZU;2-J
Abstract
The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conv ersion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl comp lex is achieved using triphenylphosphine as reductant.