Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes

Authors
Kabir, SMH Iyoda, M
Citation
Smh. Kabir et M. Iyoda, Selectivity of cyano-Gilman cuprates: synthesis of 10-membered ring cyclophanes, CHEM COMMUN, (23), 2000, pp. 2329-2330
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
23
Year of publication
2000
Pages
2329 - 2330
Database
ISI
SICI code
1359-7345(2000):23<2329:SOCCSO>2.0.ZU;2-S
Abstract
The oxidation of cyano-Gilman cuprates, derived from dibromodithienyl sulfi de, dibromodithienyldimethylsilane and dibromodithienylmethane, with molecu lar oxygen furnishes 10-membered ring cyclophanes selectively and an X-ray analysis of cyclophane 9 reveals that it possesses an anti conformation.