Aligned single-wall carbon nanotubes in composites by melt processing methods

This Letter describes the production of single-wall carbon nanotube (SWNT) - polymer composites with enhanced mechanical and electrical properties and exceptional nanotube alignment. A combination of solvent casting and melt mixing was used to disperse SWNT materials in poly(methyl methacrylate) (PM MA). Composite films showed higher conductivity along the flow direction th an perpendicular to it. Composite fibers were melt spun to achieve draw rat ios between 20 and 3600. The elastic modulus and yield strength of SWNT-PMM A composite fibers increased with nanotube loading and draw ratio. Polarize d resonant Raman spectroscopy indicates that the nanotubes in the fibers ar e well aligned, with mosaic distribution FWHMs as small as 4 degrees. (C) 2 000 Elsevier Science B.V. All rights reserved.