Time scale of short range order fluctuation in the isotropic phase of butylcyano-phenylcyclohexane liquid crystal

Citation
Fv. Chavez et al., Time scale of short range order fluctuation in the isotropic phase of butylcyano-phenylcyclohexane liquid crystal, CHEM P LETT, 330(3-4), 2000, pp. 368-372
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
330
Issue
3-4
Year of publication
2000
Pages
368 - 372
Database
ISI
SICI code
0009-2614(20001110)330:3-4<368:TSOSRO>2.0.ZU;2-H
Abstract
The NMR spin-lattice relaxation time at three Larmor frequencies - v(L) = 2 8 MHz, 1.235 MHz and 48 kHz - in the isotropic phase of butylcyano-phenylcy clohexane has been measured in the temperature range close to the isotropic -nematic phase transition. Spin-lattice relaxation mechanisms provided by b oth individual reorientational fluctuations and fluctuations of the local d irector can be distinguished at the different Larmor frequency scales. We c onclude that the Landau-De Gennes theory for the weak first order nematic-i sotropic phase transition, together the low frequency approximation can be applied if the experiment is carried out at Larmor frequencies in the kHz r ange. (C) 2000 Elsevier Science B.V. All rights reserved.