Hydroprocessing of a Maya residue. 1. Intrinsic kinetics of asphaltene removal reactions

The intrinsic kinetics of hydrocatalytic conversion of the asphaltenic frac tion from a Maya residue is reported. The kinetic study was carried out at high temperatures (375-415 degreesC) and hydrogen pressure, 12.5 MPa, in a perfectly mixed reactor in continuos operation. Asphaltenic fraction concen tration data fit half-order removal kinetics, the activation energy being 4 1.5 kcal/ mel. The relationships existing between the deasphalting and impo rtant reactions which occur in the hydroprocessing (fraction over 343 degre esC conversion, desulfuration, denitrogenation, and demetalation) were stud ied.