In this paper, recent progress in the investigation of photosensitivities o
f polymer optical fibers and the development of polymer optical fiber grati
ng is reported. Photosensitivities in various polymer fibers, including dop
ed and undoped, multimode and single-mode polymer fibers, have been experim
entally characterized and evaluated for fiber grating application. In parti
cular, the wavelength dependence of material absorption and photosensitivit
y has been found essential to the fabrication of polymer optical fiber grat
ing. Based on the results of photosensitivity research, polymer optical fib
er gratings have been successfully fabricated. More importantly, polymer op
tical fiber grating has been demonstrated highly tunable, with a tuning ran
ge more than 70 nm. The unique feature of high tunability in polymer optica
l fiber grating has great potential in various applications including optic
al fiber WDM systems and fiber sensor systems. Several important issues tha
t remain to be investigated will also be discussed.