Conjugate addition of arylmetal reagents to an alpha,beta-unsaturated ketone. Short syntheses of (-)-agatharesinol dimethyl ether and (-)-sugiresinoldimethyl ether

Authors
Matsuo, K Ono, Y Seki, A Kuwajima, H Nishiwaki, K
Citation
K. Matsuo et al., Conjugate addition of arylmetal reagents to an alpha,beta-unsaturated ketone. Short syntheses of (-)-agatharesinol dimethyl ether and (-)-sugiresinoldimethyl ether, HETEROCYCLE, 53(11), 2000, pp. 2553
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
53
Issue
11
Year of publication
2000
Database
ISI
SICI code
0385-5414(20001101)53:11<2553:CAOART>2.0.ZU;2-V
Abstract
(-)-Agatharesinol dimethyl ether and (-)-sugiresinol dimethyl ether, deriva tives of(-)-agatharesinol and (-)-sugiresinol isolated from Agathis austral is and Cryptomeria Japonica, respectively were synthesized starting from a protected D-glyceraldehyde in five steps through 1,4-conjugate addition of arylmetal reagents to an alpha,beta -unsaturated ketone.