High resolution optical (4193-6619 Angstrom) spectra of Io in eclipse show
auroral emission in five lines: [O-I] 6300, 6363, 5577 Angstrom and Na 5889
, 5896 Angstrom, We conclude that Io's diffuse red emissions imaged by the
Galileo Solid State Imager (P, E. Geissler ef al. 1999, Science 285, 870-87
4) are due to impact or dissociative excitation of oxygen, while diffuse gr
een emissions are caused by the impact or dissociative excitation of sodium
. No emission lines were detected in the blue region of the spectra, sugges
ting that the intense emission observed above Io's equatorial plumes is due
to a molecular species such as SO2 or SO. (C) 2000 Academic Press.