Observation of a large coupling of a bound dihydrogen ligand to phosphorusligands in trans-[(dppe)(2)Ru(eta(2)-H-2) (PF(OMe)(2))][BF4](2) complex

Authors
Mathew, N Jagirdar, BR
Citation
N. Mathew et Br. Jagirdar, Observation of a large coupling of a bound dihydrogen ligand to phosphorusligands in trans-[(dppe)(2)Ru(eta(2)-H-2) (PF(OMe)(2))][BF4](2) complex, INORG CHEM, 39(23), 2000, pp. 5404
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
23
Year of publication
2000
Database
ISI
SICI code
0020-1669(20001113)39:23<5404:OOALCO>2.0.ZU;2-0
Abstract
A new dicationic dihydrogen complex of the type trans-[(dppe)(2)Ru(eta (2)- H-2)(PF(OMe)(2))]BF4](2) has been prepared and characterized. A large coupl ing of about 50 Hz between the H-2 and trans-phosphorus ligand in this comp lex has been observed. [GRAPHICS]