Thermodynamic properties on mixing for hexane plus cyclohexane+1-octanol at 298.15 K

Citation
E. Mascato et al., Thermodynamic properties on mixing for hexane plus cyclohexane+1-octanol at 298.15 K, J CHEM EN D, 45(6), 2000, pp. 1154-1159
Citations number
25
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
6
Year of publication
2000
Pages
1154 - 1159
Database
ISI
SICI code
0021-9568(200011/12)45:6<1154:TPOMFH>2.0.ZU;2-3
Abstract
Density, speed of sound, isentropic compressibility, and refractive index h ave been measured for the ternary mixture hexane + cyclohexane + 1-octanol at 298.15 K and at atmospheric pressure. From these data, excess molar volu mes and excess isentropic compressibilities have been calculated. The resul ts were fitted by means of different polynomial expressions. Several empiri cal methods for predicting ternary derived properties from binary data were tested. The Nitta-Chao group contribution model was applied to predict the excess molar volume for this mixture.