Effect of carbon dioxide loading on the solubility of nitrous oxide in aqueous solutions of 2-(tert-butylamino)ethanol

Citation
B. Munder et al., Effect of carbon dioxide loading on the solubility of nitrous oxide in aqueous solutions of 2-(tert-butylamino)ethanol, J CHEM EN D, 45(6), 2000, pp. 1195-1200
Citations number
13
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
6
Year of publication
2000
Pages
1195 - 1200
Database
ISI
SICI code
0021-9568(200011/12)45:6<1195:EOCDLO>2.0.ZU;2-K
Abstract
The physical solubility of nitrous oxide was measured in aqueous solutions of 2-(tert-butylamino)ethanol. This amine is considered to be sterically hi ndered and is a candidate chemical absorbent for the selective absorption o f hydrogen sulfide in the presence of carbon dioxide. Measurements were mad e for amine concentrations up to 30 mass % over the temperature range 25 de greesC to 40 degreesC. The effect of carbon dioxide loading up to 0.90 mol of CO2/mole of amine on the nitrous oxide solubility was also investigated. The data obtained in this work may be used to estimate the physical solubi lity of carbon dioxide in these amine solutions through use of the nitrous oxide analogy method.