Physical solubility of hydrogen sulfide in aqueous solutions of 2-(tert-butylamino)ethanol

Citation
B. Munder et al., Physical solubility of hydrogen sulfide in aqueous solutions of 2-(tert-butylamino)ethanol, J CHEM EN D, 45(6), 2000, pp. 1201-1204
Citations number
7
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
6
Year of publication
2000
Pages
1201 - 1204
Database
ISI
SICI code
0021-9568(200011/12)45:6<1201:PSOHSI>2.0.ZU;2-E
Abstract
The physical solubility of hydrogen sulfide in aqueous solutions of 2-(tert -butylamino)ethanol neutralized with hydrochloric acid was measured in this work. Measurements were made over the temperature range 25 degreesC to 40 degreesC and the amine concentration range 0 to 50 mass %. The solubility d ata exhibit a minimum in the solubility with amine concentration. The data were correlated using the van-Krevelen-Hoftijzer method for the "salting-ou t" effect up to the minimum solubility and by a new empirical method over t he entire range of amine concentration.