Ss. Seomun et al., Alignment instability caused by anchoring of the in-plane directors to therubbing direction in the V-shaped switching, J MAT CHEM, 10(12), 2000, pp. 2791-2794
In order to investigate the molecular alignment in the smectic liquid cryst
als showing the V-shaped switching behavior, two types of the liquid crysta
l cells, a sandwiched cell and an open cell, were prepared. Homogeneous ali
gnment with the smectic layer normal formed at similar to 12 degrees with r
espect to the rubbing direction n is obtained in the Sm-A phase in both cel
ls. However, in the open cell, the director n is rotated towards r when the
Sm-A sample is cooled into the tilted Sm-X* phase. In addition, its maximu
m rotation angle is similar to 12 degrees. In this configuration, the molec
ules lie along r. Meanwhile, the sandwiched cell with the one-side rubbing
treatment exhibits the averaged optical axis almost parallel to the layer n
ormal in the Sm-X* phase. In this paper, a simple small-twisted state in th
e thin sandwiched cell is suggested to account for the experimental results
.