Influence of gaseous atmosphere on corona-induced degradation of aqueous phenol

The phenol degradation processes by pulsed corona discharges are investigat ed under three kinds of discharge atmosphere lair, argon and oxygen). The t emporal variations of the concentrations of phenol and the intermediate pro ducts are monitored by LIF spectroscopy. The species of the intermediate pr oducts are identified by spectral analysis. It is clarified that the oxidat ive gaseous reagents produced from O-2 and those from H2O degrade phenol to intermediate products with comparable degradation rates. The degradation v ia the reagents from H2O gives rise to the formation of molecules exhibitin g fluorescence at 400-500 MI, in addition to dihydroxybenzene (DHB), while the degradation via the reagents from O-2 produces only DHB. The reagents f rom O-2 play an important role in the conversion of phenol to DHB.