Potential formation near a negative charge collecting substrate in a negati
ve ion plasma was studied experimentally. We present the first observation
of a potential double layer formed in front of a positively biased substrat
e in pure SF6 discharge plasma. With the increase of SF6 gas in Ar gas, the
plasma potential reduced to negative potential, which is lower than the wa
ll potential. The energy distribution function of the negative charges in S
F6 plasma predicted the presence of negative ions near the sheath edge and
its disappearance at a position close to the substrate. This result implies
that negative ions are kept inside the bulk plasma by the sheath electric
field while few of them can reach the surface of the substrate.