A theory is presented to explain the stretching and orientation of a semifl
exible chain such as the biopolymeric filamentous actin and deoxyribonuclei
c acid in a magnetic field. Both dilute and concentrated solutions are cons
idered. The theory predicts the requirement of a high magnetic field to ach
ieve a high degree of orientation in a dilute solution. The experimental va
lue of the order parameter for a dilute, polydisperse F-actin solution has
been compared with the theoretical value. On the other hand, a molecular fi
eld (nematic liquid crystal) which exists in a concentrated solution can ac
hieve the same effects of stretching and orientation and can be assisted by
a magnetic field. Sources of diamagnetic anisotropy in biopolymers have be
en cited, (C) 2000 John Wiley & Sons, Inc.