Synthesis and characterization of solid coordination complexes of diamidesfor uranium(VI) and thorium(IV)

Authors
Wang, YS Yang, AP Zhou, GF Tan, XF
Citation
Ys. Wang et al., Synthesis and characterization of solid coordination complexes of diamidesfor uranium(VI) and thorium(IV), J RAD NUCL, 246(2), 2000, pp. 419-422
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
ISSN journal
02365731 → ACNP
Volume
246
Issue
2
Year of publication
2000
Pages
419 - 422
Database
ISI
SICI code
0236-5731(200011)246:2<419:SACOSC>2.0.ZU;2-N
Abstract
Five kinds of solid coordination complexes of uranium(VI) and thorium(IV) w ith the diamide (N,N,N',N'-tetrabutylmalon-amide (TBMA), N,N,N',N'-tetrabut ylsuccinylamide (TBSA), N,N,N',N'-tetrabutylglutaramide (TBGA), N,N,N',N'-t etrabutyl-adipicamide (TBAA)) were synthesized. All these complexes of UO2( NO3)(2). TBMA, UO2(NO3)(2). TBSA, [UO2(NO3)(2). (TBGA(1/2))(2)](x), UO2(NO3 )(2). TBAA and Th(NO3)(4). 2TBMA were characterized by elemental analysis, UV spectra, IR spectra and C-13 NMR spectra. The coordination form and prop osed structures of the complexes are also discussed.