Kc. Galbreath et al., Nickel speciation of residual oil fly ash and ambient particulate matter using X-ray absorption spectroscopy, J AIR WASTE, 50(11), 2000, pp. 1876-1886
Citations number
38
Categorie Soggetti
Environment/Ecology,"Environmental Engineering & Energy
The chemical speciation of Ni in fly ash produced from similar to0.85 wt %
S residual (no. 6 fuel) oils in laboratory (7 kW)- and utility (400 MW)-sca
le combustion systems was investigated using X-ray absorption fine structur
e (XAFS) spectroscopy, X-ray diffraction (XRD), and acetate extraction [1 M
NaOAc-0.5 M HOAc (pH 5) at 25 degreesC]-anodic stripping voltammetry (ASV)
. XAFS was also used to determine the Ni speciation of ambient particulate
matter (PM) sampled near the 400-MW system. Based on XAFS analyses of bulk
fly ash and their corresponding acetate extraction residue, it is estimated
that >99% of the total Ni (0.38 wt %) in the experimentally produced fly a
sh occurs as NiSO4. xH(2)O, whereas >95% of the total Ni (1.70 and 2.25 wt
%) in two fly ash samples from the 400-MW system occurs as NiSO4. xH(2)O an
d Ni-bearing spinel, possibly NiFe2O4. Spinel was also detected using XRD.
Acetate extracts most of the NiSO4. xH(2)O and concentrates insoluble NiFe2
O4 in extraction residue. Similar to fly ash, ambient PM contains NiSO4. xH
(2)O and NiFe2O4; however, the proportion of NiSO4. xH(2)O relative to NiFe
2O4 is much greater in the PM. Results from this and previous investigation
s indicate that residual oil ash produced in the 7-kW combustion system lac
k insoluble Ni (e.g., NiFe2O4) but are enriched in soluble NiSO4. xH(2)O re
lative to fly ash from utility-scale systems. This difference in Ni speciat
ion is most likely related to the lack of additive [e.g., Mg(OH)(2)] inject
ion and residence time in the 7-kW combustion system.