A combined experimental and density functional theory investigation of hydrocarbon activation at a cationic platinum(II) diimine aqua complex under mild conditions in a hydroxylic solvent
H. Heiberg et al., A combined experimental and density functional theory investigation of hydrocarbon activation at a cationic platinum(II) diimine aqua complex under mild conditions in a hydroxylic solvent, J AM CHEM S, 122(44), 2000, pp. 10831-10845
Controlled protonolysis of (N-f-N-f)Pt(CH3)(2) (1; N-f-N-f = ArN=CMe-CMe=NA
r, Ar = 3,5-(CF3)(2)C6H3) with NBF4. Et2O in dichloromethane in the presenc
e of small quantities of water gives the BF4- salt of the aqua complex (N-f
-N-f)Pt(CH3)(H2O)(+) (6). When dissolved in trifluoroethanol (TFE), 6(BF4-)
effects the activation of methane and benzene C-H bonds under very mild co
nditions. Thus, 6 reacted with benzene in TFE-d(3) at ambient temperature t
o quantitatively yield (N-f-N-f)Pt(C6H5)(H2O)(+) and methane after 2-3 h. T
he use of C6D6 led to multiple incorporation of deuterium into the methane
produced and suggests the involvement of methane sigma -complex and benzene
sigma- or pi -complex intermediates. When the solution of 6(BF4-) was expo
sed to (CH4)-C-13, an exchange reaction produced ca. 50% of (N-f-N-f)Pt((CH
3)-C-13)(H2O)(+) and CH4 after ca. 48 h at 45 degreesC. The reaction was in
hibited by added water, suggesting that water is reversibly lost from 6 bef
ore C-II activation takes place. The use of CD4 resulted in multiple deuter
ium incorporation into the methane produced, again implying a Pt-methane si
gma -complex intermediate. Low-temperature protonation of 1 in dichlorometh
ane-d(2) generated observable Pt(IV) hydride species (N-f-N-f)Pt(CH3)(2)(H)
(L)(+). These decomposed via methane elimination, raising the possibility t
hat the observed C-H activation proceeds by an oxidative addition pathway.
The reaction between 6 and CH4 was investigated by DFT calculations using a
model system with the HN=CH-CH=NH ligand. The C-H activation was investiga
ted for oxidative addition and sigma -bond metathesis pathways starting fro
m the four-coordinate methane complex (N-N)Pt(CH3)(CH4)(+). The oxidative a
ddition pathway, thermodynamically uphill by 23 kJ/mol (ZPE-corrected data)
, was favored by 12 kJ/mol relative to the sigma -bond metathesis. When a H
2O ligand was added to the five-coordinate oxidative addition product, the
overall oxidative addition reaction was thermodynamically downhill by 33 kJ
/mol (partially ZPE-corrected) starting from an H2O adduct of (N-N)Pt(CH3)(
CH4)(+) with H2O electrostatically bonded at the diimine moiety. In this ca
se, the oxidative addition pathway was favored by 20 kJ/mol. The calculatio
ns indicated that reductive elimination of methane from the six-coordinate
(N-N)Pt(CH3)(2)(H)(H2O)(+) with the hydride and H2O ligands trans disposed
occurred in concert with dissociation of the aqua ligand.