Chitosan: A natural polymeric support of catalysts for the synthesis of fine chemicals

The high surface hydrophilicity of chitosan is the property which has allow ed the synthesis of an efficient, selective, and stable palladium supported aqueous phase catalyst for the reaction of allylic substitution of (E)-cin namyl ethyl carbonate by morpholine. The adjustment of the water content of the catalytic solid and the addition of a cationic surfactant (CTAB) in th e medium both contribute to improve drastically the efficiency of the catal yst while keeping the palladium leaching below 0.5%.