Palladium-catalysed asymmetric [4+2] cycloaddition of vinylallene with 1,3-diene

Citation
M. Murakami et al., Palladium-catalysed asymmetric [4+2] cycloaddition of vinylallene with 1,3-diene, PHYS CHEM P, 2(23), 2000, pp. 2293-2294
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2293 - 2294
Database
ISI
SICI code
1463-9076(2000)2:23<2293:PA[COV>2.0.ZU;2-Y
Abstract
A catalytic asymmetric [4 + 2] cycloaddition reaction of a vinylallene with buta-1,3-diene was developed in which a palladium complex modified by a fe rrocene-derived chiral monophosphine ligand acted as a template transferrin g chirality to the product.