The first unambiguous determination of a nitrosyl-to-nitrite conversion inan iron nitrosyl porphyrin

Authors
Cheng, L Powell, DR Khan, MA Richter-Addo, GB
Citation
L. Cheng et al., The first unambiguous determination of a nitrosyl-to-nitrite conversion inan iron nitrosyl porphyrin, PHYS CHEM P, 2(23), 2000, pp. 2301-2302
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2301 - 2302
Database
ISI
SICI code
1463-9076(2000)2:23<2301:TFUDOA>2.0.ZU;2-#
Abstract
The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conv ersion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl comp lex is achieved using triphenylphosphine as reductant.