Highly stable cage-like complexes by self-assembly of tetracationic Zn(II)porphyrinates and tetrasulfonatocalix[4]arenes in polar solvents

Authors
Fiammengo, R Timmerman, P de Jong, F Reinhoudt, DN
Citation
R. Fiammengo et al., Highly stable cage-like complexes by self-assembly of tetracationic Zn(II)porphyrinates and tetrasulfonatocalix[4]arenes in polar solvents, PHYS CHEM P, 2(23), 2000, pp. 2313-2314
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2313 - 2314
Database
ISI
SICI code
1463-9076(2000)2:23<2313:HSCCBS>2.0.ZU;2-L
Abstract
Tetracationic Zn(II) porphyrinates and tetraanionic calix[4]arenes can be a ssembled in polar solvents to obtain cage-like complexes in an entropy driv en process. These structures are remarkably stable even in the presence of water or competing salts.