A highly convergent synthesis of a branched C-trisaccharide employing a double SmI2-promoted C-glycosylation

Authors
Mikkelsen, LM Krintel, SL Jimenez-Barbero, J Skrydstrup, T
Citation
Lm. Mikkelsen et al., A highly convergent synthesis of a branched C-trisaccharide employing a double SmI2-promoted C-glycosylation, PHYS CHEM P, 2(23), 2000, pp. 2319-2320
Citations number
26
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2319 - 2320
Database
ISI
SICI code
1463-9076(2000)2:23<2319:AHCSOA>2.0.ZU;2-B
Abstract
The branched C-trisaccharide analogue of alpha -D-Man-(1 -->3)-[alpha -D-Ma n-(1 -->6)]-D-Man has been synthesised by the SmI2-mediated coupling of two mannosyl pyridyl sulfone units to a monosaccharide dialdehyde. This approa ch represents a highly convergent synthesis of a C-oligosaccharide.