Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams

Authors
Jackson, LV Walton, JC
Citation
Lv. Jackson et Jc. Walton, Generation of aminoacyl radicals from 1-carbamoyl-1-methylcyclohexa-2,5-dienes: a new tin-free homolytic route to beta- and gamma-lactams, PHYS CHEM P, 2(23), 2000, pp. 2327-2328
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
ISSN journal
14639076 → ACNP
Volume
2
Issue
23
Year of publication
2000
Pages
2327 - 2328
Database
ISI
SICI code
1463-9076(2000)2:23<2327:GOARF1>2.0.ZU;2-O
Abstract
Radical induced homolyses of 1-carbamoyl-1-methylcyclohexa-2,5-dienes took place cleanly to yield aminoacyl radicals, with no competition from the alt ernative dissociation to methyl radicals: beta- and gamma -lactams were obt ained from ring closures of suitably unsaturated model compounds.